MOF-derived porous hierarchical ZnCo2O4 microflowers for enhanced performance gas sensor

作者：Li, Xin; Zhang, Yunzhuo; Cheng, Yue; Chen, Xujun; Tan, Wenhu^*

来源：Ceramics International, 2021, 47(7): 9214-9224.

DOI：10.1016/j.ceramint.2020.12.047

• Zn_Co-ZIF
• ZnCo2O4
• Hierarchical structure
• Microflowers
• Gas sensor

Metal-organic framework (MOF)-derived ZnCo2O4 was synthesized by utilizing the template agent 2-methylimidazole, zinc and cobalt nitrate by an easy solvothermal process followed by annealing for the first time. The porous hierarchical ZnCo2O4 microstructure possesses a microflower structure assembled by 3D nanosheets. The obtained flower-like structure has abundant open spaces between nanosheets, which allows for facile gas diffusion while providing plentiful active sites for gas adsorption. The hierarchical ZnCo2O4 microflower-based sensor exhibits a high response of 32.32 and fast response/recovery rates (2.6/8.8 s) at 200 degrees C to 100 ppm acetone gas. In addition, the porous hierarchical ZnCo2O4 microflower-based sensor has a detection limit below 50 ppb with a response of 2.51 to acetone gas. The excellent sensing performance of this porous hierarchical structure-based sensor is ascribed to the good gas accessibility of the microflower morphology with a high specific surface area, small particle size and highly porous structure. This work explores an efficient way to synthesize MOF-derived bimetallic oxides with microflower structures assembled by 3D nanosheets for gas sensing applications.