科研之友
微信
新浪微博
Facebook
分享链接
摘要
A Lewis acid catalyzed carbofunctionalization of styrenes with diacyl peroxides and nucleophiles, including amines, indoles, trimethoxybenzenes, and carboxylic acid, has been accomplished. A wide range of primary, secondary, and tertiary alkyl diacyl peroxides generated from inexpensive aliphatic acids serve as both simple alkylating reagents and internal oxidants for the synthesis of value-added amines, indoles, 1,1-diarylalkanes, and esters in moderate to good yields. This protocol features site selectivity, broad substrate scope, and mild reaction conditions.
-
单位南昌航空大学; 厦门大学
