Ti3C2Tx as electron-hole transfer mediators to enhance AgBr/BiOBr Z heterojunction photocatalytic for the degradation of Tetrabromobisphenol A: Mechanism Insight

作者：Huang, Shuhong; Wang, Yan^*; Wan, Jinquan; Yan, Zhicheng; Ma, Yongwen; Zhang, Guihua; Wang, Silong

来源：Applied Catalysis B: Environmental , 2022, 319: 121913.

DOI：10.1016/j.apcatb.2022.121913

• Z-scheme
• BiOBr/Ti(3)C(2)Tx /AgBr
• High redox ability
• Electron-hole mediated
• TBBPA toxicity assessment

In this study, BiOBr/Ti(3)C(2)Tx/AgBr ternary materials were successfully synthesized by a two-step method. The photocatalytic performance of the prepared materials was systematically evaluated. The results showed excellent light trapping ability and carrier separation efficiency of prepared BiOBr/Ti(3)C(2)Tx /AgBr, the photodegradation efficiency of TBBPA was 97.16% within 60 min, and the degradation rate was 1.8 times higher than BiOBr/AgBr. The enhanced photocatalytic efficiency of BiOBr/Ti(3)C(2)Tx /AgBr is attributed to the increased light-harvesting capacity and the fast transport and separation of photogenerated electron-hole in the Z-scheme structure. In situ irradiation X-ray photoelectron spectroscopy (ISI-XPS) successfully revealed Ti(3)C(2)Tx as a channel for rapid electron-hole transfer in Z-scheme heterojunctions. In addition, the TBBPA degradation pathways and toxicity changes were further explored by LC-MS and toxicity assessment. Ti(3)C(2)Tx as an electron-hole transfer medium for the construction of Z-scheme photocatalysts can provide new ideas for the structural design of new high-efficiency photocatalysts.

• 单位
  中国科学院; y; 惠州学院; 中国科学院研究生院