Highly Selective Transport and Enrichment of Lithium Ions through Bionic Ion Pair Receptor Nanochannels

作者：Li, Guang; Wang, Yue; Luan, Hanghang; Sun, Yue^*; Qu, Yanjuan^*; Lu, Zhiyan^*; Li, Haibing^*

来源：ACS applied materials & interfaces, 2023, 15(27): 32753-32761.

DOI：10.1021/acsami.3c05776

• lithium ion
• ion pair recognition
• pillararene-basedreceptors
• host-guest systems
• bionic nanochannel

Inspired by ion pair cotransport channels in biologicalsystems,a bionic nanochannel modified with lithium ion pair receptors is constructedfor selective transport and enrichment of lithium ions (Li+). NH2-pillar[5]arene (NP5) is chosen as ion pair receptors,and the theoretical simulation and NMR titration experiments illustratethat NP5 has good affinity for the ion pair of LiCl through a stronghost-guest interaction at the molecular level. Due to the confinementeffect and ion pair cooperation recognition, an NP5-based receptorwas introduced into an artificial PET nanochannel. An I-V test indicated that the NP5 channel realized the highly selectiverecognition for Li+. Meanwhile, transmembrane transportand COMSOL simulation experiments proved that the NP5 channel achievedthe transport and enrichment of Li+ through the cooperativeinteraction between NP5 and LiCl. Moreover, the receptor solutionof transmembrane transport LiCl in the NP5 channel was used to cultivatewheat seedlings, which obviously promoted their growth. This nanochannelbased on the ion pair recognition will be much useful for practicalapplications like metal ion extraction, enrichment, and recycle.

• 单位
  y; 武汉大学