A hybrid aluminum/hydrogen/air cell system

作者：Wang L; Wang W; Yang G; Liu D; Xuan J; Wang H; Leung M K H; Liu F^*

来源：International Journal of Hydrogen Energy, 2013, 38(34): 14801-14809.

DOI：10.1016/j.ijhydene.2013.09.036

• Aluminum air battery
• Hybrid cell system
• Hydrogen air fuel cell
• Membraneless fuel cell
• Parasitic self-corrosion reaction
• Passive fuel cell

A hybrid aluminum/hydrogen/air cell system is developed to solve the parasitic hydrogen-generating problem in an alkaline aluminum/air battery. A H2/air fuel cell is integrated into an Al/air battery so that the hydrogen generated by the parasitic reaction is utilized rather than wasted. A systematic study is conducted to investigate how the parasitic reaction and the added H2/air cell affect the performance of the aluminum/air battery. The aluminum/air sub-cell has an open circuit voltage of 1.45 V and the hydrogen/air sub-cell of 1.05 V. The maximum power density of the entire hybrid system increases significantly by ∼20 after incorporating a H 2/air sub-cell. The system maximum power density ranges from 23 to 45 mW cm-2 in 1-5 M NaOH electrolyte. The hybrid system is adaptable in concentrated alkaline electrolyte with significantly improved power output at no sacrifice of its overall efficiency.