Unveiling heterogeneous microstructure and good combinations of high yield strength and low coercivity of in-situ formed NbC/FeNiCo medium-entropy composites

作者：Chu, Chenliang; Chen, Weiping; Fu, Zhiqiang^*; Wang, Hao; Jiang, Zhenfei; Xiong, Wei; Chen, Qiang

来源：Powder Technology, 2023, 419: 118365.

DOI：10.1016/j.powtec.2023.118365

• Medium-entropy composites (MECs)
• Spark plasma sintering (SPS)
• Heterogeneous structures
• Mechanical properties
• Soft-magnetic properties

It is very challenging to achieve exceptional combinations of soft-magnetic and mechanical properties in conventional soft-magnetic alloys. To tailor combinations of soft-magnetic and mechanical properties, different volume fractions of in-situ formed NbC were designedly introduced into the recently emerged equi-atomic FeNiCo medium-entropy alloy displaying appealing soft-magnetic properties but disappointing strength. The bulk NbC/FeNiCo medium-entropy composite (MEC) with -7.8 vol% NbC (MEC7.5) consisted of ultra-fine and fine FCC grains with nano-sized NbC, realized the best combinations of mechanical and soft-magnetic properties. In detail, it showed an ultra-high tensile yield strength of -1158 MPa and an improved elongation of -4.6%, resulting from dislocation strengthening, dispersion strengthening and hetero-deformation induced strengthening. Simultaneously, the saturation magnetization and coercivity of the MEC7.5 were - 143 emu/g and - 382