Robust single-piece all-solid-state potassium-selective electrode with monolayer-protected Au clusters

Authors：An, Qingbo; Jiao, Liansheng; Jia, Fei; Ye, Junjin; Li, Fenghua; Gan, Shiyu; Zhang, Qixian; Ivaska, Ari; Niu, Li^*

Source：Journal of Electroanalytical Chemistry, 2016, 781: 272-277.

DOI：10.1016/j.jelechem.2016.10.053

• Ion selective electrode
• Au clusters
• Single-piece electrodes
• Electrochemical sensor

High stability of the signal and simplicity in fabrication of the device are the two important requirements in development of potentiometric sensors, A robust single-piece all-solid-state potassium-selective electrode (K-SPE) was developed by incorporating monolayer-protected Au clusters (MPCs) as advanced ion-to-electron transducers into a conventional ion-selective membrane (ISM). The extraordinary properties of MPCs such as high solubility, profound hydrophobicity and large capacitance make them quite suitable to be used in fabrication of single-piece electrodes (SPEs) with advanced performance. The developed KSPEs containing small amount of MPCs in the membrane showed a significant increase in the potential stability (12.9 mu V/h), lower detection limit (10(-6.1) M) and prolonged life time (high performance still after 3 weeks). The multi-valence MPCs in the membrane facilitated the ion-to-electron transduction and fast establishment of the potential equilibrium resulting in-fast response time in potential measurements. The inserted MPCs did not cause any interference either in the potential formation process or in the selectivity of the ion-selective membrane.