Construction of an α-Fe2O3/Bi2O3 p-n heterojunction with exceptional visible-light photocatalytic performance for dye removal

作者：Lei, Rui; Wei, Jinlong; He, Wanzhu; Ao, Xiuqin; Song, Jinqiang^*; Wang, Chao^*; Zhang, Quanquan^*; Xie, Hao^*; Li, Jing; Ni, Jiamiao

来源：New Journal of Chemistry, 2022.

DOI：10.1039/d0nj02132f

• NANOTUBE ARRAYS
• WATER OXIDATION
• BAND-GAP
• DEGRADATION
• EFFICIENT
• HETEROSTRUCTURES
• NANOCOMPOSITE
• NANOPARTICLES
• FABRICATION
• NANORODS

alpha-Fe2O3/Bi2O3 nanocomposites with a p-n heterojunction were synthesized via an anodization strategy and the hydrothermal method for photocatalytic applications. By changing the hydrothermal treatment time, Bi2O3 nanosheets were deposited on the surface of alpha-Fe2O3 nanotube arrays (NTAs). The morphologies and photochemical performance of the as-prepared alpha-Fe2O3/Bi2O3 nanocomposites were investigated in detail. The presence of Bi2O3 nanosheets resulted in an obvious red-shift in the UV-Vis diffuse reflectance spectrum, indicating that the alpha-Fe2O3/Bi2O3 nanocomposites had an expanded visible light photo-response range. The alpha-Fe2O3/Bi2O3 nanocomposites displayed excellent photocatalytic activity, stability and recyclability toward the decomposition of methylene blue under visible light illumination. The photocurrent and electrochemical impedance spectra also testified efficient electron transport and charge separation in the alpha-Fe2O3/Bi2O3 nanocomposites. The enhanced photocatalytic performance can be ascribed to a high light harvesting ability, fast separation of photogenerated electron-hole pairs and the presence of an efficient interfacial electric field from the p-n heterojunction. The photogenerated holes and superoxide radicals played crucial roles in the photocatalytic process. The photocatalytic mechanism was discussed.