Construction of a chiral zinc-camphorate framework for enantioselective separation

作者:Zhu, Chengfeng*; Wang, Hongzhao; Mu, Yongfei; Zhang, Ziwei; Cheng, Lanjun; Li, Tianfu; Fu, Yanming; Wu, Xiang; Li, Yougui*
来源:Dalton Transactions, 2022, 51(25): 9627-9631.
DOI:10.1039/d2dt01221a

摘要

A chiral metal-organic framework (CMOF) with open chiral channels and multiple recognition sites is constructed from camphoric acid and a dipyridyl ligand. It can act as an efficient chiral solid adsorbent, capable of separating a variety of racemic alcohols and epoxides with excellent enantioselectivities.