Adsorption of Fluorocarbons and Chlorocarbons by Highly Porous and Robust Fluorinated Zirconium Metal-Organic Frameworks

作者:Wang, Hao*; Yu, Liang; Lin, Yuhan; Peng, Junjie; Teat, Simon J.; Williams, Lawrence J.; Li, Jing*
来源:Inorganic Chemistry, 2020, 59(7): 4167-4171.
DOI:10.1021/acs.inorgchem.0c00018

摘要

Fluorocarbons and chlorocarbons are common volatile organic compounds that pose serious risk to the environment and human health and therefore need to be effectively captured. Herein, we report a series of highly fluorinated metal-organic frameworks with high porosity (Brunauer-Emmett-Teller surface area similar to 3000 m(2)/g) and stability. They show exceptionally high capacity and good recyclability toward the adsorption of fluorocarbons and chlorocarbons.