Unprecedented one-dimensional chain and two-dimensional network dysprosium(iii) single-molecule toroics with white-light emission

作者：Zhong, Li; Chen, Wen-Bin; OuYang, Zhi-Jian; Yang, Meng; Zhang, Yi-Quan^*; Gao, Song^*; Schulze, Michael; Wernsdorfer, Wolfgang; Dong, Wen^*

来源：Chemical Communications, 2020, 56(17): 2590-2593.

DOI：10.1039/c9cc08852k

• COUPLING DY-3 TRIANGLES
• GROUND-STATE
• ION
• MAGNETIZATION
• BLOCKING
• MOMENTS
• MAGNET

One-dimensional zig-zag chain and two-dimensional network dysprosium(iii) single-molecule toroics with anisotropy barriers of about 5 and 31 cm(-1) under a zero dc field are reported. These are the first one- and two- dimensional homometallic single-molecule toroics reported to date. Furthermore, the two complexes also display white-light emission under UV-light irradiation.

• 单位
  广州大学; 1