Fabricating Black-Phosphorus/Iron-Tetraphosphide Heterostructure via a Solid-Phase Solution-Precipitation Method for High-Performance Nitrogen Reduction

作者：Bian, Shi; Liu, Qian; Zhang, Xue^*; Ma, Chao; Zhang, Yanli; Cheng, Ziqiang; Kang, Yihong; Lu, Wei; Chu, Paul K.; Yu, Xue-Feng; Wang, Jiahong^*

来源：Small, 2022, 18(39): 2203284.

DOI：10.1002/smll.202203284

• black phosphorus
• heterostructures
• iron tetraphosphide
• nitrogen reduction
• solid-phase synthesis

Although constructing heterostructures is considered as one of the most successful strategies to improve the activity of a catalyst, the heterostructures usually suffer from the cumbersome preparation treatments and low-yield. Inspired by a solid-phase solution-precipitation (SPSP) process, an approach for interface intensive heterostructures with high yield is developed. Herein, a black-phosphorus/iron-tetraphosphide (BP/FeP4) heterostructure is prepared mechanochemically with high transient pressure by the solid-phase ball milling approach. The BP/FeP4 heterostructure delivers excellent catalytic performance in the nitrogen reduction reaction (NRR) as exemplified by an NH3 yield of 77.6 mu g h(-1) mgcat.-1\[{\rm{mg}}_{{\rm{cat}}{\rm{.}}}<^>{{\bm{ - }}1}\] and Faradic efficiency of 62.9% (-0.2 V), which are superior to that of most NRR catalysts recently reported. Experimental investigation and density-functional theory calculation indicate the importance of excess phosphorus in the heterostructures on the NRR activity, which assists the Fe atom to activate N-2 via adsorbing the H atom. The results demonstrate the great potential of this new type of heterostructures prepared by the SPSP approach. Benefiting from the simple preparation process and low cost, the heterostructures offer a new insight into the development of highly efficient catalysts.

• 单位
  中国科学院