Fast and efficient aqueous arsenic removal by functionalized MIL-100(Fe)/rGO/δ-MnO2 ternary composites: Adsorption performance and mechanism

摘要

Because of its significant toxicological effects on the environment and human health, arsenic (As) is a major global issue. In this study, an Fe-based metal-organic framework (MOF) (Materials of Institut Lavoisier: MIL-100 (Fe)) which was impregnated with reduced graphene oxide (rGO) by using a simple hydrothermal method and coated with birnessitetype manganese oxide (delta-MnO2) using the one-pot reaction process (MIL-100(Fe)/rGO/delta-nanocomposites) was synthesized and applied successfully in As removal. The removal efficiency was rapid, the equilibrium was achieved in 40 min and 120 min for As(III) and As(V), respectively, at a level of 5 mg/L. The maximum adsorption capacities of As(III) and As(V) at pH 2 were 192.67 mg/g and 162.07 mg/g, respectively. The adsorbent revealed high stability in pH range 2-9 and saturated adsorbent can be fully regenerated at least five runs. The adsorption process can be described by the pseudo-second-order kinetic model and Langmuir monolayer adsorption. The adsorption mechanisms consisted of electrostatic interaction, oxidation and inner sphere surface complexation.

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