Mn4+ non-equivalent doped fluoride phosphors with a short fluorescence decay time for backlighting

作者：Li, Jie; Yang, Xinyi; Li, Tong; Ye, Yanqing; Zhou, Yayun^*; Wang, Qin; Zhou, Qiang; Wang, Zhengliang^*

来源：Dalton Transactions, 2022, 51(6): 2512-2516.

DOI：10.1039/d1dt04191f

• RED PHOSPHOR

The non-equivalent doping of Mn4+ in red-emitting fluoride phosphors effectively shortens the fluorescence lifetime. Herein, we successfully synthesized Rb2NaInF6:Mn4+ phosphors by an ion-exchange method. The compensation mechanism of Mn4+ local symmetry and charge balance in the phosphor were studied in detail by theoretical calculations based on density functional theory. The phosphor Rb2NaInF6:Mn4+ (5.59 mol%) exhibits intense red emission with a short fluorescence lifetime (1.45 ms). Meanwhile, it has excellent colour stability and thermal quenching stability at elevated temperatures. Using Rb2NaInF6:Mn4+, beta-SiAlON:Eu2+ and a blue-emitting GaN chip as red, green, and blue components, the white light-emitting diode (w-LED) exhibits a wide colour gamut of 94.1% of the National Television System Committee (NTSC) standard value. So, this work provides valuable information to investigate novel red-emitting fluoride phosphors for LED backlighting.

• 单位
  云南大学