Coordination-driven self-assembly of MOF-based heterostructures for electrocatalytic methanol oxidation

作者：Chang, Xi-Wen; Wang, Yan-Jiang; Wu, Xue-Qian^*; Wu, Ya-Pan; Li, Shuang; Liu, Yunling; Li, Yong-Shuang; Li, Dong-Sheng^*

来源：Journal of Solid State Chemistry, 2023, 323: 124035.

DOI：10.1016/j.jssc.2023.124035

• Metal-organic framework
• Bimetallic oxide
• Heterogeneous electrocatalyst
• Methanol oxidation

Direct methanol fuel cells (DMFCs) are considered one of the most promising energy conversion devices due to their environmentally friendly and high-energy density features. However, the sluggish anode kinetics of the methanol oxidation reaction (MOR) acts as a bottleneck in the DMFCs system. Herein, a series of MOF-based heterogeneous electrocatalysts (NiWO4/MOF-74-chi, Ni3V2O8/MOF-74-chi) is constructed via a coordinationdriven self-assembly strategy to enhance the catalytic property of the MOR. The heterogeneous interface between MOF-74 and Ni compounds is built by the Ni -O coordination interaction, which provides fast charge transfer and mass diffusion efficiency. Therefore, the optimal catalyst NiWO4/MOF-74 (3) exhibits excellent MOR activity and operation durability with a peak current density of 28.58 mA center dot cm(-2). This work is expected to inspire the design of more efficient MOF-based heterogeneous electrocatalysts for MOR and other energy conversion applications.

• 单位
  吉林大学