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Bronsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines

Gui, Jiao; Xie, Haisheng; Chen, Fengjuan; Liu, Zhipeng; Zhang, Xiaoqi; Jiang, Fubin; Zeng, Wei*
Science Citation Index Expanded
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摘要

A Bronsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines in the presence of TPT and CF3CO2H has been developed. This transformation provides a green approach to alpha-amino-substituted arylalkanes under metal-free conditions.

关键词

CATALYZED INTERMOLECULAR HYDROAMINATION AMINATION ALCOHOLS ALKYLATION ANILINES AMINES C(SP(3))-H COMPLEXES