科研之友
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摘要
A Rh(III)-catalyzed oxidative 1,3-aryl migration of alpha-arylallylic alcohols via Csp(2)-Csp(3) sigma bond activation has been developed. This method provides an efficient strategy to allow for allylic alcohol-based skeleton rearrangement, in which various secondary and tertiary alpha-arylallylic alcohols are rapidly converted to beta-aryl-alpha, beta-unsaturated ketones and aldehydes.
