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A non-enzymatic photoelectrochemical sensor based on g-C3N4@CNT heterojunction for sensitive detection of antioxidant gallic acid in food

Li, Jiaodi; Wang, Chenxi; Chen, Xiaoling; Huang, Minghui; Fu, Qian; Li, Rongjie; Wang, Yilin; Li, Chunyan; Zhao, Pengcheng*; Xie, Yixi; Fei, Junjie*
Science Citation Index Expanded
湘潭大学

摘要

Gallic acid (GA) is found in a wide range of natural plants and is relevant to the health of human beings. Here, a photoelectrochemical sensing platform based on g-C3N4@CNT heterojunction has been prepared for the highly sensitive and selective detection of GA. Under the light of xenon lamp, the photocurrent of g-C3N4@CNT is 7 times higher than that of g-C3N4 And the sensor generates 4 times more photocurrent in the presence of GA than without GA. This sensor has a wide linear range from 10 nM to 10 mu M with a limit of detection as low as 2 nM. Also, the abundant amino groups of g-C3N4 provide excellent selectivity for the sensor. Furthermore, the sensor can be used for the analysis of GA in black tea samples, which provides a novel and rapid method for the detection of GA in food samples.

关键词

Photoelectrochemical sensor g-C3N4@CNT heterojunction Gallic acid Electron-hole pairs