Facet- and defect-engineered Pt/Fe2O3 nanocomposite catalyst for catalytic oxidation of airborne formaldehyde under ambient conditions

作者：Chen, Muhua; Yin, Hui; Li, Xiaoyin; Qiu, Yuping; Cao, Guoxuan; Wang, Jiajun; Yang, Xianfeng; Wang, Ping^*

来源：Journal of Hazardous Materials, 2020, 395: 122628.

DOI：10.1016/j.jhazmat.2020.122628

• Formaldehyde catalytic oxidation
• Surface engineering
• Pt-based catalyst
• Octadecahedral Fe2O3
• High index facet

Formaldehyde (HCHO) is one of the most infamous indoor pollutants that imposes a great threat to human health. Herein, we report the development of a high-performance Pt/Fe2O3 catalyst for HCHO oxidation employing a facet- and defect-engineering strategy, with special focus on the surface structure effect of alpha-Fe2O3 on the catalytic properties. A supported N nanocatalyst on hollow octadecahedral alpha-Fe2O3 with exclusively exposed {113} and {104} facets was prepared using a hydrothermal method followed by impregnation-reduction treatment. The high-index facets of alpha-Fe2O3 render the formation of abundant oxygen vacancies and an improved dispersion of N nanoparticles. This led to an increased Pt/O-vacancy coexistence in close proximity, which collaboratively promote the generation of active oxygen and surface OH species. As a consequence, the Pt/Fe2O3-HO catalyst exhibited impressively high and stable activity towards HCHO oxidation at room temperature, which was five-fold higher than that of the supported N catalyst on commercial alpha-Fe2O3.