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The In-Situ Observation of Grain Rotation and Microstructure Evolution Induced by Electromigration in Sn-3.0Ag-0.5Cu Solder Joints

Fu, Xing; Liu, Min*; Xu, KeXin; Chen, Si; Shi, YiJun; Fu, ZhiWei; Huang, Yun; Chen, HongTao*; Yao, RuoHe*
Science Citation Index Expanded
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摘要

The in-situ observation of Sn-3.0Ag-0.5Cu solder joints under electromigration was conducted to investigate the microstructure and grain orientation evolution. It was observed that there was a grain rotation phenomenon during current stressing by in-situ electron backscattered diffraction (EBSD). The rotation angle was calculated, which indicated that the grain reorientation led to the decrease of the resistance of solder joints. On the other hand, the orientation of beta-Sn played a critical role in determining the migration of Cu atoms in solder joints under current stressing migration. When the angle between the electron flow direction and the c-axis of Sn (defined as alpha) was close to 0 degrees, massive Cu6Sn5 intermetallic compounds were observed in the solder bulk; however, when alpha was close to 90 degrees, the migration of the intermetallic compound (IMC) was blocked but many Sn hillocks grew in the anode. Moreover, the low angle boundaries were the fast diffusion channel of Cu atoms while the high grain boundaries in the range of 55 degrees-65 degrees were not favorable to the fast diffusion of Cu atoms.

关键词

electromigration in-situ EBSD grain rotation Sn hillock grain boundary