Rational design of three Co(II) coordination polymers based on a semirigid tricarboxylate ligand: Syntheses, structural variability, electrochemical behavior, magnetic and photocatalytic properties

Authors：Wang, Cheng-feng; Wang, Jianxun; Wang, Xin-ping; Zhang, Xiaoyin; Meng, Yao; Chen, Fushan; Lin, Liangxu^*; Meng, Xiang-min^*

Source：Journal of Molecular Structure, 2022, 1265: 133439.

DOI：10.1016/j.molstruc.2022.133439

• Coordination polymers
• N-donor configuration
• Electrochemical behavior
• Magnetic property
• Photocatalytic activity

Three novel Co(II) based coordination polymers (CPs) are fabricated using the 5-(2carboxylphenoxy)isophthalic acid (H 3 L) and different N-donor configuration under the solvothermal conditions, namely, [Co 2 (L)(1,4-bibt)( mu 3 -OH)] n ( 1 ), [Co(HL)(4,4 ' -bidpe)] n ( 2 ), and [Co(HL)(tib)] n ( 3 ) (1,4-bibt = 1,4-bis(imidazol-1-yl)butane, 4,4 ' -bidpe = 4,4 ' -bis(imidazolyl)diphenylether, tib = 1,3,5tris(1-imidazolyl)benzene). The configuration of 1 -3 are confirmed by various characterization analysis. The CP 1 possesses an unprecedented (3,10)-connected 3D architecture with a unique tetranuclear [Co 4 (mu 3 -OH) 2 (COO) 4 ] 2 + cluster. Interestingly, when the H 3 L ligands are not calculated, the whole structure of N-donor still shows a 3-fold interpenetrating dia 3D framework (3D + 3D -> 3D). Moreover, CPs 2 and 3 are 3D supramolecular structure with significant differences structures. The CP 2 shows a 2D sql uninodal 4-connected 2D network with the Schlafli symbol (4 4 center dot 6 2 ), while CP 3 exhibits an unprecedented 2D framework. And both 2 and 3 construct 3D supramolecular architecture through H-bonds between the two adjacent 2D networks. Comparing CPs 1 -3 shows that the N-donor ligands play a key role in adjusting the final structures. Furthermore, the electrochemical behavior, magnetic properties and photocatalytic activity of 1 -3 are also discussed in details.

• Institution
  中国科学院青岛生物能源与过程研究所