An inorganic-rich SEI induced by LiNO3 additive for a stable lithium metal anode in carbonate electrolyte

作者:Liu, Dongdong; Xiong, Xunhui*; Liang, Qianwen; Wu, Xianwen; Fu, Haikuo
来源:Chemical Communications, 2021, 57(73): 9232-9235.
DOI:10.1039/d1cc03676a

摘要

The dissolution of LiNO3 in carbonate electrolytes is achieved by introducing pyridine as a new carrier solvent owing to its higher Gutmann donor number than NO3-. The Li metal anode in LiNO3-containing carbonate electrolyte demonstrates a much enhanced reversibility due to the preferential reduction of LiNO3 and the formation of an inorganic-rich SEI.