A water-stable dual-responsive Cd-CP for fluorometric recognition of hypochlorite and acetylacetone in aqueous media

作者：Wang, Yan-Ning^*; Xu, Hao; Wang, Shao-Dan; Mao, Run-Yu; Wen, Lin-Man; Wang, Si-Yuan; Liu, Lin-Jie; Sun, Yue; Lu, Shu-Qin; Wang, Fan; Yang, Qing-Feng

来源：Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy , 2023, 286: 121952.

DOI：10.1016/j.saa.2022.121952

• Coordination polymer
• Fluorescence
• Hypochlorite
• Acetylacetone

One novel cadmium(II)-coordination polymer [Cd3L2(datrz)(H2O)3] (CP 1) is controllably synthesized by surmising the astute combination of semi-rigid tricarboxylate acid 4-(2 ',3 '-dicarboxylphenoxy) benzoic acid (H3L) and auxiliary ligand 3,5-diamino-1,2,4-triazole (datrz). Structure analysis shows that CP 1 has a two-dimensional (2D) layer structure with a 5-nodal (43) (44.62) (45.64.8) (45.6) (47.66.82) topology. Further in-vestigations reveal that CP 1 shows superordinary water stability and good thermal stability. The fluorescent explorations suggest that the as-synthesized CP 1 could emit blue light centered at 485 nm, attributing to ligand- based emission. In terms of sensing investigations, CP 1 could act as a fluorescent sensor for detecting hypo -chlorite (ClO-) and acetylacetone (acac) through fluorescence turn-off process in aqueous solution, and the detection limit could reach 0.18 mu M and 0.056 mu M, respectively. Further research reveals that it is more likely the N-H center dot center dot center dot O-Cl hydrogen bonds between -NH2 groups of the triazole ligands and O atoms of ClO- plays the key role in the system, which may serve as a bridge for the energy transfer, leading to fluorescence quenching of the chemosensor. While the photoinduced electron transfer (PET) combined with inner filter effect (IFT) should be responsible for the turn-off fluorescence of CP 1 triggered by acac.