Molecular beam epitaxy, photoluminescence from Mn2+multiplets and self-trapped exciton states of ?-MnTe single-crystalline thin films

作者：Cao, Hechun; Zhang, Jiyue; Bai, Wei^*; Zhao, Dongyang; Lin, Ruobing; Wang, Xudong; Yang, Jing; Zhang, Yuanyuan; Qi, Ruijuan; Huang, Rong; Tang, Xiaodong^*; Wang, Jianlu; Chu, Junhao

来源：Applied Surface Science, 2023, 611: 155733.

DOI：10.1016/j.apsusc.2022.155733

• ?-MnTe
• Molecular beam epitaxy
• Mn 2+ions d
• d multiplets transition
• D -electrons
• Self -trapped excitons state

Single-crystalline gamma-MnTe thin films with zinc-blende structure were grown epitaxially on InP(1 1 1) by molecular beam epitaxy. Two-dimensional growth regime and atomic surface flatness are achieved, and appearance of Laue's oscillation peaks illustrates the superior crystalline quality and interface of gamma-MnTe films. A pseudocrystal buffer layer is formed at interface releasing the strain led by the large lattice mismatch between gamma-MnTe and InP, and then growth of gamma-MnTe films with a perfect lattice evidences the high-quality crystallinity in a fully relaxed state. Photoluminescence (PL) emissions from 4T1g(4G) and 4T1(4G) related to Mn2+ ions d-d multiplets are observed with their respective activation energies of -142.5 meV and -323.5 meV. Such high potentials reflecting the nonradiative recombination indicate the thermal stability of these PL. Moreover, two extra PL transitions assigned to be the emissions from self-trapped exciton (STE) states are found below TN. Time-resolved PL (TRPL) spectra at various temperatures indicate that the relaxation dynamics of photoexcited d-electrons is strongly correlated to the antiferromagnetic ordering transition due to the synergy of magnon, phonon and STE states. These findings suggest that introduction of STE states in a material by controlling its magnetic ordering qualifies the competition in optoelectronics devices.

• 单位
  中国科学院; 中国科学院研究生院; 复旦大学