Nanoarchitectonics from 2D to 3D: MXenes-derived nitrogen-doped 3D nanofibrous architecture for extraordinarily-fast capacitive deionization

作者：Ding, Zibiao; Xu, Xingtao^*; Li, Jiabao; Li, Yuquan; Wang, Kai; Lu, Ting; Hossain, Md Shahriar A.; Amin, Mohammed A.; Zhang, Shuaihua; Pan, Likun^*; Yamauchi, Yusuke^*

来源：Chemical Engineering Journal, 2022, 430: 133161.

DOI：10.1016/j.cej.2021.133161

• MXenes
• Nanofibrous architectures
• Capacitive deionization
• Nitrogen doping
• Desalination

Two-dimensional (2D) nanosheets are promising electrode materials for electrochemical desalination by capacitive deionization (CDI). Like most 2D nanosheets, the delicate design of MXene-based materials can achieve state-of-the-art desalination capacities, but the intrinsic low ion diffusion characteristic of 2D nanosheets limits the desalination rate. To address this problem, we synthesize a new-family of nitrogen-doped threedimensional (3D) nanofibrous architectures from MXenes (denoted as N-TNF) via direct alkalization and subsequent nitrogenization of common MXene stacks. N-TNF has a unique nanofiber structure and plentiful nitrogen dopants, resulting in expanded interlayer spacing, high specific surface area and excellent electrochemical activity. As a result, the N-TNF shows an ultrahigh mean desalination rate of 5.6 mg g(-1) min(-1), along with superior desalination capacity of 44.8 mg g(-1), as well as good long-term cycling stability, which is comparable to state-ofthe-art MXene electrodes and better than most 2D materials. This work demonstrates the fabrication of MXenederived 3D materials, and provides a new approach to overcome the limits of 2D nanosheets for efficient CDI.

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