Room Temperature Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and Fluorescence Properties of One Novel Cubane Zinc Cluster Based on 1-{2-Hydroxy-3-[(2-Hydroxy-3-Methoxy-Benzylidene)-Amino]-Phenyl}-Ethanon e

作者：Zhou, Tao; Zhang, Haiyang; Zhang, Shu-Hua^*; Hu, Zhenguang^*

来源：RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 67(SUPPL 1): S35-S41.

DOI：10.1134/S0036023622601817

• room temperature synthesis
• Hirshfeld surface analysis
• fluorescence
• molecular structure

One novel distorted cubane zinc cluster, [Zn-4(L)(4)]& BULL;(DMF)(2) (1, H2L = 1-{2-Hydroxy-3-[(2- hydroxy-3-methoxy-benzylidene)-amino]-phenyl}-ethanone, DMF = N,N'-dimethyl-formamide), was obtained by room temperature synthesis. The cluster was characterized using elemental analysis, powder X-ray diffraction, IR spectroscopy, and single-crystal X-ray diffraction. 1 is a cubane zinc cluster. The L ligand of 1 displays two different coordination modes: One is the mu(3)-L-kappa O-6(1),N-1,O-2:O-2:O-2,O-3 and the other is mu(2)-L-kappa O-5(1),O-2:O-2,N-1,O-3 coordination modes. Hirshfeld surface analysis revealed that H & BULL;& BULL;& BULL;H interaction was the most abundant intermolecular interaction. The cluster emits a red fluorescence of 622 at 517 nm excite.

• 单位
  茂名学院; 桂林理工大学