Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research

作者：Zheng, Xuchen; Chen, Siao; Li, Jinze; Wu, Han; Zhang, Chao; Zhang, Danyan; Chen, Xi; Gao, Yang; He, Feng; Hui, Lan; Liu, Huibiao; Jiu, Tonggang; Wang, Ning; Li, Guoxing; Xu, Jialiang; Xue, Yurui^*; Huang, Changshui^*; Chen, Chunying; Guo, Yanbing; Lu, Tong-Bu; Wang, Dan; Mao, Lanqun; Zhang, Jin; Zhang, Yue; Chi, Lifeng; Guo, Wanlin; Bu, Xian-He; Zhang, Hongjie; Dai, Liming; Zhao, Yuliang; Li, Yuliang^*

来源：ACS Nano, 2023, 17(15): 14309-14346.

DOI：10.1021/acsnano.3c03849

• graphdiyne
• two-dimensional carbon materials
• controlled growth
• atomic catalysis
• energy conversion
• life science
• intelligent device
• materialseparation

Graphdiyne(GDY), a rising star of carbon allotropes,featuresa two-dimensional all-carbon network with the cohybridization of spand sp(2) carbon atoms and represents a trend and researchdirection in the development of carbon materials. The sp/sp(2)-hybridized structure of GDY endows it with numerous advantages andadvancements in controlled growth, assembly, and performance tuning,and many studies have shown that GDY has been a key material for innovationand development in the fields of catalysis, energy, photoelectricconversion, mode conversion and transformation of electronic devices,detectors, life sciences, etc. In the past ten years, the fundamentalscientific issues related to GDY have been understood, showing differencesfrom traditional carbon materials in controlled growth, chemical andphysical properties and mechanisms, and attracting extensive attentionfrom many scientists. GDY has gradually developed into one of thefrontiers of chemistry and materials science, and has entered therapid development period, producing large numbers of fundamental andapplied research achievements in the fundamental and applied researchof carbon materials. For the exploration of frontier scientific conceptsand phenomena in carbon science research, there is great potentialto promote progress in the fields of energy, catalysis, intelligentinformation, optoelectronics, and life sciences. In this review, thegrowth, self-assembly method, aggregation structure, chemical modification,and doping of GDY are shown, and the theoretical calculation and simulationand fundamental properties of GDY are also fully introduced. In particular,the applications of GDY and its formed aggregates in catalysis, energystorage, photoelectronic, biomedicine, environmental science, lifescience, detectors, and material separation are introduced.

• 单位
  南京航空航天大学; 中国科学院; 清华大学; 南开大学; 北京科技大学; y; 北京大学; 苏州大学; 国家纳米科学中心; 中国科学院研究生院; 山东大学