科研之友
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摘要
Double perovskites exhibit low toxicity, intrinsic thermodynamic stability, and small carrier effective mass. Herein, a novel doping route was adopted to incorporate Mn ions into Cs2Na1-xAgxBiCl6 double perovskites for engineering the band gap and tailoring the energy transfer. The as-prepared Cs2Na1-xAgxBiCl6 (0 < x < 1) exhibited excellent photoluminescence and a broad self-trapped exciton (STE) band from 500 to 900 nm, which exhibited an abnormal emission peak blue shift with increasing temperature. For Mn-doped Cs2Na1-xAgxBiCl6, the two photoluminescence (PL) bands from d-d transition emission of Mn ions and STEs were always observed simultaneously in the PL The distinct energy-transfer channel from the Mn2+ ion guest to the double-perovskite host resulted in the dominant Mn2+ emission. Our results will be helpful for further understanding the nature of the photophysics of double perovskites.
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