Full biomass-based multifunctional flocculant from lignin and cationic starch

作者：Sun, Danting; Zeng, Jia; Yang, Dongjie; Qiu, Xueqing; Liu, Weifeng^*

来源：International Journal of Biological Macromolecules, 2023, 253: 127287.

DOI：10.1016/j.ijbiomac.2023.127287

• Lignin
• Cationic starch
• Wastewater treatment

Flocculation is a common process for wastewater treatment. However, the most commonly used organic synthetic flocculants such as polyacrylamide are petroleum-based. In this work, biomass lignin was grafted with cationic starch to synthesize low-cost, green and fully biomass-based multifunctional flocculants. The cationic polyacrylamide was replaced by cheap industrial cationic starch. Hyperbranched multifunctional lignin-grafted cationic starch flocculant (CS-L) was successfully prepared via ring-opening reaction with epichlorohydrin. The mass content of lignin in the grafted product was between 16.6 % and 70.1 %. With the dosage of CS-L between 4.0 and 7.5 mg/l, the turbidity removal rate for 500 mg/l kaolin suspension reached more than 97 %. When the dosage of CS-L was 24 mg/l, the removal rate of 50 mg/l Cu2+ reached 85.7 %. Importantly, when the mixed solution of kaolin particles and Cu2+ was treated, the synchronous removal rates of kaolin and Cu2+ reached 90 % and 72 % respectively in the range of 8.0-12.0 mg/l flocculant addition. The synthesized lignin-grafted cationic starch flocculant showed an excellent multifunctional flocculation function.

• 单位
  广东工业大学