Interpenetration, Self-Catenation, and New Topology in Metal-Organic Frameworks of Cobalt with Mixed Organic Linkers

作者：Zhang, Jian Yong; Jing, Xue Hui; Ma, Yu; Cheng, Ai Ling; Gao, En Qing^*

来源：Crystal Growth and Design, 2011, 11(9): 3681-3685.

DOI：10.1021/cg200120p

• COORDINATION POLYMERS
• INDUSTRIAL APPLICATIONS
• NETS
• LIGAND
• ZINC
• POLYOXOMETALATE
• CHEMISTRY
• NETWORKS
• PROPERTY
• DATABASE

Two Co(II) metal organic frameworks with 2, 2'-dinitrobipheny1-4,4'-dicarboxylate (dnpdc) and different dipyridyl ligands have been synthesized by hydrothermal methods. They exhibit different three-dimensional mixed-connected net topologies with either interpenetration or self-catenation features. With dnpdc and 4,4'-bipyridine as cobridging ligands, compound 1 displays 3-fold interpenetrated (4,6)-connected nets based on mononuclear and binuclear nodes. With dnpdc and bis(4-pyridl)ethane as cobridging ligands, compound 2 exhibits a novel (6,8)-connected net based on two different binuclear nodes, with a high degree of self-catenation arising from the interconnection of "interpenetrated" 2D subnets.

• 单位
  华东师范大学