Effect of electron structure on the catalytic activity of LaCoO3 perovskite towards toluene oxidation

作者：Chen, Hanlin; Liu, Peng; Wei, Gaoling; Huang, Yu; Lin, Xiaoju; Liang, Xiaoliang^*; Zhu, Jianxi

来源：Chemical Communications, 2022, 58(30): 4731-4734.

DOI：10.1039/d2cc00404f

• OXIDES

LaCoO3 perovskites with different spin states of Co3+ were prepared by calcination at 600-1000 degrees C. LaCoO3 with electron filling in the e(g) orbital at 1 exhibited a moderate interaction between the surface oxygen, resulting in the best catalytic activity. This was verified by the O p-band center.

• 单位
  中国科学院; 中国科学院研究生院; 茂名学院