Manganese-doped cobalt tetroxide for formaldehyde oxidation

作者：Li, Guangyao; Chen, Muhua; Huang, Xuelin; Wang, Ping^*

来源：Journal of Environmental Chemical Engineering, 2022, 10(5): 108328.

DOI：10.1016/j.jece.2022.108328

• Formaldehyde oxidation
• Earth-abundant catalyst
• Cobalt-based oxide
• Substitutional doping
• Oxygen vacancy

Cobalt-based oxides are appealing but less-well investigated catalytic materials for formaldehyde (HCHO) oxidation. We herein report a careful study of carbon-supported Co(3_x)Mn(x)O4 catalyst, with special focuses on the incorporation of Mn ions into Co3O4 lattice and its effect on the catalytic activity for HCHO oxidation. The Co3_xMnxO4/C catalysts were fabricated using a co-precipitation method followed by annealing treatment. A combination of phase structure/chemical structure analyses and control experiments confirmed the substitu-tional doping of Mn ions in Co3O4 lattice, which resulted in increment of oxygen vacancy concentration. Benefiting from Mn-doping and the dispersion effect of carbon, the Co2.7Mn0.3O4/C catalyst prepared under optimal conditions exhibited an impressively high activity for HCHO oxidation, fairly good stability and excellent moisture tolerance. For instance, it enabled a 100% HCHO conversion at 90 C with a ten-fold higher mass -specific activity compared to Co3O4/C. A possible mechanism describing the HCHO oxidation over Co3_xMnxO4/C catalyst was proposed based on the in situ diffused reflectance infrared spectroscopy results.