Synergistic Modification for Efficient Perovskite Solar Cells with Small Voltage Loss

Authors：He, You; Dong, Hua; Chen, Cong; Hao, Feng; Long, Fei; Wang, Jilin^*; Zuo, Chuantian^*; Ding, Liming

Source：ACS applied materials & interfaces, 2023, 15(44): 51072-51078.

DOI：10.1021/acsami.3c10430

• perovskite solar cells
• two-step method
• defectpassivation
• interfacial modification
• energy loss

The power conversion efficiency (PCE) of perovskite solar cells has improved quickly in the past few years, but the PCE is still much lower than the theoretical limit. The relatively high energy loss (E-loss) is one of the critical factors limiting the PCE. To resolve the above issues, a synergistic modification strategy was used herein to minimize E-loss. RbCl and potassium polyacrylate (K-PAM) were used to modify the SnO2 layer. Additionally, Pb(Ac)(2) was introduced into PbI2 to further improve the film quality. The synergistic modification strategy reduced the defects in SnO2 and perovskite and improved the energy-level alignment, enabling significantly reduced E-loss and enhanced photovoltaic performance. The best PCE of 24.07% was achieved, which was much higher than that of the control device (20.86%). The E-loss was only 0.349 eV for the target device. Good stability was achieved for the cells made using modified SnO2 and perovskite layers.

• Institution
  西安交通大学; 桂林理工大学; 中国科学院; 电子科技大学; 国家纳米科学中心