Number of optical floating zone melting passes dependence of the LaB6 single crystals

作者：Bao, Yan; Wang, Yan^*; Luo, Shifeng; Cai, Minghui; Deng, Chenhui; Yang, Xinyu; Zhang, Jiuxing

来源：Journal of Crystal Growth, 2022, 593: 126785.

DOI：10.1016/j.jcrysgro.2022.126785

• B1
• LaB 6 single crystal
• A2
• Number of optical floating zone melting
• passes
• A1
• Crystal quality
• Crystal purity
• Thermionic emission properties

LaB6 materials, especially single crystals, are a kind of ideal cathode materials, however, the number of optical floating zone melting passes dependence of the LaB6 single crystals are still unknown. In this paper, the effect of the number of optical floating zone melting passes on the crystal quality, purity and properties of LaB6 single crystals has been investigated. It was found that a truly [1 00] LaB6 single crystal consisting of no sub-grains or twin crystals was successfully grown regardless of how many zone melting passes. The crystal quality and purity have been verified to be gradually improved with the increase of the number of zone melting passes. It was particularly notable that there were very small differences in the content of impurity elements between as-grown crystals after two or three zone melting passes. The excellent performances of J1kV = 42.22 A/cm2, Jo = 28.99 A/ cm2 and phi eff = 2.66 eV were belonged to LaB6 single crystal after two zone melting passes, which indicates that the method of two optical floating zone melting passes is the most suitable at present for the growth of highquality, high-purity and high-performance LaB6 single crystals.

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