Construction and two-dimensional assembly of double-shell Na@Sn6L6@Sn3L3 clusters through tetrahedral citrate ligands

作者：Zhu, Yu; Li, Dongsheng^*; Zhang, Jian; Zhang, Lei^*

来源：Chemical Communications, 2022, 58(37): 5650-5652.

DOI：10.1039/d2cc01824a

• METAL-ORGANIC FRAMEWORK
• DISCRETE
• DRIVEN
• CAGE
• TIN
• CRYSTAL
• CHAIN
• INTERCONVERSION
• SN-6

Herein we report double-shell Na@Sn6L6@Sn3L3 clusters and their further assembly into a 2D layer, which belongs to a rare Sn-oxo coordination cage-based extended structure. Tetrahedral citrate ligands with multiple coordination sites play key roles in such hierarchical assembly.

• 单位
  中国科学院福建物质结构研究所