Conversion of nonporous helical cadmium organic framework to a porous form

作者：Gu Zhi Gang; Cai Yue Peng^*; Fang Hua Cai; Zhou Zheng Yuan; Thallapally Praveen K; Tian Jian; Liu Jun; Exarhos Gregory J

来源：Chemical Communications, 2010, 46(29): 5373-5375.

DOI：10.1039/c0cc01042a

Two novel cadmium-organic frameworks containing achiral helical nanotubular channels, [Cd(HImDC)(S)](n) (S = Im(1) and Py(2)), have been synthesized and characterized using single crystal X-ray diffraction, in which 1 converts to 2 upon refluxing 1 in pyridine solution with noticeable porosity and hydrogen uptake at medium pressure.

• 单位
  华南师范大学