Mechanochemically Induced Cross Dehydrogenative Coupling Reactions under Ball Milling

作者：Egorov, Ilya N.; Mukherjee, Anindita; Santra, Sougata^*; Kopchuk, Dmitry S.; Kovalev, Igor S.; Liu, Yuanli; Zyryanov, Grigory V.; Majee, Adinath; Chupakhin, Oleg N.; Ranu, Brindaban C.^*

来源：Advanced Synthesis and Catalysis, 2022, 364(15): 2462-2478.

DOI：10.1002/adsc.202200296

• Cross Dehydrogenative Coupling Reactions
• Ball milling
• Green Procedure
• C-C Bond Formation
• C-Heteroatom Bond Formation
• Asymmetric CDC

Cross dehydrogenative coupling (CDC) reactions have become a convenient synthetic strategy for the synthesis of various (het)aromatic scaffolds. In recent times ball milling has emerged as a powerful tool to perform reactions in a greener way. The current review highlights various applications of cross dehydrogenative coupling reactions under ball milling towards synthesis of useful molecules in a more efficient and convenient manner. @@@ 1. Introduction @@@ 2. Discussion @@@ 2.1. DDQ-Mediated Reactions @@@ 2.2. Reactions in Presence of Hypervalent Iodonium Reagents @@@ 2.3. Reactions in Presence of Transition Metal Catalysts Combined with Other Oxidants @@@ 3. Conclusions

• 单位
  i; 桂林理工大学