A soluble iron(ii)-phthalocyanine-catalyzed intramolecular C(sp3)-H amination with alkyl azides

摘要

Herein, we describe a soluble iron(ii)-phthalocyanine, [Fe-II((Bu4Pc)-Bu-t)(py)(2)] (Pc = phthalocyaninato(2-)), as an effective catalyst in intramolecular C(sp(3))-H bond amination, with alkyl azides as the nitrogen source, to afford the amination products in moderate to excellent yields with a broad substrate scope.

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