A Ruddlesden-Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures

摘要

Solid oxide fuel cells (SOFCs) that operate at intermediate temperatures of 600 to 800 degrees C have recently received increased attention due to their improved durability, more rapid startup and shutdown, better sealing and lower cost than their counterparts operate at high temperatures. Nevertheless, intermediate-temperature SOFCs (IT-SOFCs) with popular perovskite cathodes contain alkaline-earth elements, which are prone to reaction with carbon dioxide (CO2), even when the CO2 content is comparatively low. In this work, an alkaline-earth metal-free Ruddlesden-Popper oxide, Nd1.8La0.2Ni0.74Cu0.21Ga0.05O4+delta (NLNCG), is developed for IT-SOFC cathodes. The cell is based on an electrolyte with 8% (mol) Y2O3-stabilized ZrO2 (8YSZ). The NLNCG cathode exhibits an excellent CO2 tolerance, as proven by thermogravimetry analysis, in situ X-ray diffraction, I-V-P test, and electrochemical impedance spectroscopy (EIS), and stability measurements. The anode-supported single-cell NiO-YSZ|YSZ|NLNCG outputs a peak power density of 0.522 W center dot cm(-2) at 800 degrees C. These findings suggest that NLNCG could be a highly suitable cathode material with CO2 tolerance for IT-SOFCs.

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