Controlled structure preparation of low thermal conductivity Bi4B2O9 foams

作者：Chen, Pan; Li, Yuanbing^*; Yin, Bo; Li, Shujing; Wang, Hailu; Qiao, Zhe; Liu, Jingfei

来源：International Journal of Applied Ceramic Technology, 2023, 20(4): 2412-2421.

DOI：10.1111/ijac.14352

• Bi4B2O9
• foam ceramics
• pore size distribution
• process parameter
• thermal conductivity

In this contribution, Bi4B2O9 foam ceramics with porosity of 76.6%-85.8% and thermal conductivity of .062-.092(W/(m center dot K)) were successfully prepared for the first time by the foam casting method using bismuth oxide and boric acid as the main raw materials and gelatin as the gel forming agent. The effects of additive content and solid loading on the slurry, pore size, and distribution as well as mechanical and thermal properties of porous ceramics were investigated. The addition of gelatin led to the stable arrangement of the liquid-gas interface, which eventually resulted in a foam with a stable pore structure. The sintered ceramics have a highly spherical morphology with typical micropores and cell window, which may also contribute to the low thermal conductivity of Bi4B2O9 foams. Bi4B2O9 foam with tailored properties and graded pore structure by adjusting the process parameters can be used as a high-performance nuclear reactor insulation material.