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Carbon defects promoting syngas into liquid fuels over Fe3C@C catalysts

Fu, Zhiyuan; Luo, Dan; Chen, Lei; Wei, Yuxue*; Ren, Mingyang; Wang, Wenjing; Zhang, Chenghua; Sun, Song
Science Citation Index Expanded
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摘要

Carbon wrapped iron catalysts have been intensively studied in recent years to achieve efficient syngas conversion into high-value-added chemicals. A Fe3C@C catalyst with defect-rich graphite shell exhibits C5+ selectivity of 70.1% and CH4 selectivity of 9.0% at CO conversion of 55.2%, which can be attributed to the enhanced reactant adsorption and anti-oxidation of Fe3C during FTS.

关键词

FISCHER-TROPSCH SYNTHESIS OXYGEN REDUCTION DOPED GRAPHENE PARTICLE-SIZE NANOPARTICLES HYDROCARBONS ADSORPTION PHASE