High-performance BaZr0.1Ce0.7Y0.1Yb0.1O3 -δ (BZCYYb) protonic ceramic fuel cell electrolytes by the Ba evaporation inhibition strategy

作者：Zhong, Zhaoyu; Song, Tao; Zhao, Shikai; Sun, Haibin^*; Guo, Xue; Feng, Yurun; Hu, Qiangqiang

来源：Ceramics International, 2024, 50(2): 3633-3640.

DOI：10.1016/j.ceramint.2023.11.113

• Protonic ceramic fuel cell
• Barium cerate
• Grain boundary
• Space-charge layer

BaZr0.1Ce0.7Y0.1Yb0.1O3-delta (BZCYYb) as a potential candidate for protonic ceramic fuel cells (PCFCs) electrolytes, often suffers from its high sintering temperature, making it deviate from the stoichiometric ratio and present a poor electrochemical performance than expected. Here, we reported a Ba evaporation inhibition strategy to fabricate stoichiometric BZCYYb electrolyte. By using this strategy, Ba evaporation and Y2O3/Yb2O3 segregation can be effectively suppressed. The electrolyte's average grain size is similar to 5.29 mu m, significantly promoting grain growth. An improvement of 60 % in total conductivity is accomplished at 700 degrees C in humid air, approaching 2.7 x 10(-2) S cm(-1). By constructing the proton transport model, the reasons for the enhanced electrochemical performance are explained from both bulk and grain boundary. Finally, at 700 degrees C, an anode-supported single cell with stoichiometric BZCYYb electrolyte demonstrates a maximum power density of 0.65 W cm(-2), showing that the barium evaporation inhibition strategy is a powerful tool to fabricate PCFCs with high performance.

• 单位
  山东理工大学