Effect of interaction from the reaction of carboxyl/epoxy hyperbranched polyesters on properties of feedstocks for metal injection molding

摘要

The purpose of this study is to improve the properties of the feedstocks and shape retention of debinded parts by the reaction between 17-4PH stainless steel powders. Carboxyl-terminated hyperbranched polyester (CTHP) and epoxy-terminated hyperbranched polyester (ETHP) were used to treat the powders, and termed as CTHP-m and ETHP-m with carboxyl and epoxy group, respectively. Comparing with pristine, CTHP-m and ETHP-m, feedstock prepared from equal amount of CTHP-m and ETHP-m (CTHP-m/ETHP-m) possessed more excellent properties. The experimental results showed that the critical solids loading, flexural modulus, density and melt flow index of CTHP-m/ETHP-m feedstock were 63.8 vol.%, 2800 Mpa, 5.06 g cm(-3) and 62 g/10 min, respectively, which were obviously higher than that of others. Also, the shape retention of CTHP-m/ETHP-m debinded parts was the best of all the samples. The improved properties of CTHP-m/ETHP-m feedstock were attributed to the powder interaction between CTHP-m and ETHP-m formed by the chemical reaction between epoxy and carboxyl group.

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