A new 3D helical silver(I) cluster metal-organic framework with microporous structure and luminescent property

摘要

A new 3D helical silver(I) metal-organic polymer of {[Ag-2(ADC)(bib)(0.5)]center dot H2O}(n) (1) (H(2)ADC = 1,3-adamantanedicarboxylic acid, bib = 1,4-bis(2-methyl-imidazol-1-yl)butane), has been synthesized and characterized. Compound 1 exhibits significant void space that may be filled with guest H2O molecules in spite of the metal-cluster that occurs in the solid. Preliminary thermal and fluorescence experiments show that compound 1 possesses strong fluorescent property and thermal stability, respectively.

关键词