Electrosynthesis of sulfonamides from DMSO and amines under mild conditions

作者:Lin, Zhiguan; Huang, Liangbin*; Yuan, Gaoqing*
来源:Chemical Communications, 2021, 57(29): 3579-3582.
DOI:10.1039/d1cc00026h

摘要

With DMSO as the solvent and the precursor of a -SO2Me unit at room temperature, a novel electrochemical oxidization and amination of DMSO with amines was developed for the synthesis of sulfonamides. Our investigations reveal that this transformation may involve a radical process and an electrochemical oxidization of DMSO.