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Electrosynthesis of sulfonamides from DMSO and amines under mild conditions

Lin, Zhiguan; Huang, Liangbin*; Yuan, Gaoqing*
Science Citation Index Expanded
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摘要

With DMSO as the solvent and the precursor of a -SO2Me unit at room temperature, a novel electrochemical oxidization and amination of DMSO with amines was developed for the synthesis of sulfonamides. Our investigations reveal that this transformation may involve a radical process and an electrochemical oxidization of DMSO.

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