NiFeOxHy with electron-deficient Ni2+ for oxygen evolution in mild media

作者：Zhong, Dazhong; Wang, Dong; Li, Tan; Hao, Lu; Ma, Zizai; Zhao, Tao; Hao, Genyan; Wang, Xiaoguang; Liu, Guang; Li, Jinping; Zhao, Qiang^*

来源：Journal of Power Sources, 2023, 556: 232444.

DOI：10.1016/j.jpowsour.2022.232444

• NiFeOxHy
• Electron-deficient Ni2+
• Amorphous
• Mild condition
• Oxygen evolution reaction

NiFe-layered double hydroxide (NiFe-OH) is one of the most promising candidate materials for the oxygen evolution reaction (OER) in an alkaline electrolyte. However, it is difficult to be oxidized into Ni3+FeOOH active species with high valence Ni under mild conditions; thus, the activity under mild conditions is inferior. We report here that NiFe-OH is converted to amorphous NiFeOxHy (a3-NiFe-OH) with easily oxidized electron-deficient Ni2+ after pre-oxidation in an alkaline solution boosts the OER performance under mild conditions. The amorphous structure of a3-NiFe-OH also enlarges the electrochemically active area to expose more active sites. It merely needs an overpotential of 350 mV at 10 mA cm(-2) in 0.1 M KHCO3 electrolyte. The corresponding Tafel slope is as low as 89 mV dec(-1). This work affords a strategy for developing (near) neutral OER catalysts.