High temperature Fe(iii) spin crossover behaviours in three unprecedented FeIII-MII-FeIII (M = Fe, Cd) linear trinuclear complexes

作者：Ouyang, Zhi-Jian; Mo, Xiao-Ying; Yang, Meng; Zhong, Li; Chen, Wen-Bin; Gao, Song; Dong, Wen^*

来源：Inorganic Chemistry Frontiers, 2020, 7(7): 1526-1531.

DOI：10.1039/c9qi01560d

• CRYSTAL TRANSFORMATION
• SOLVENT
• 2-STEP
• SERIES
• CHAIN
• STATE
• EPR

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H(3)ATD) was used to synthesize three unprecedented Fe-III-M-II-Fe-III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe-III ions.

• 单位
  广州大学