In situ formation of Cu-Sn bimetallic catalysts for CO2 electroreduction to formate with high efficiency

作者：Dong, Xue; Sun, Xiaofu; Jia, Shuaiqiang; Han, Shitao; Yao, Ting; Zhou, Dawei; Xie, Yijun; Xia, Wei; Wu, Haihong^*; Han, Buxing^*

来源：Catalysis Science & Technology, 2023, 13(8): 2303-2307.

DOI：10.1039/d3cy00236e

• ELECTROCATALYTIC CONVERSION
• CARBON-DIOXIDE
• REDUCTION
• SELECTIVITY
• SURFACE

In this work, we proposed a method to prepare Cu-Sn bimetallic catalysts, which are composed of Cu-0, Sn-0, and SnO2 by combination of a hydrothermal process and in situ electrochemical reduction. The catalysts exhibited efficient electrocatalytic activity towards the conversion of CO2 to formate with a faradaic efficiency of 92.9% and a current density of 632 mA cm(-2). The partial current density was very high comparing with other Sn-based catalysts reported. The presence of Cu promoted the existence of electron-deficient centers and realized the regulation of Cu on Sn, which promoted the protonation reaction of CO2-, leading to improved activity and selectivity to formate.

• 单位
  中国科学院