Interface-enhanced organic solar cells with extrapolated T80 lifetimes of over 20 years

摘要

With recent advances in the power conversion efficiency (PCE) of organic solar cells (OSCs) based on novel donor and non-fullerene acceptor (NFAs), improving the stability of these systems has become the most important issue for their practical applications. Herein, an efficient and highly stable OSC, containing a novel polymer donor and a non-fullerene acceptor system, is reported. The OSC is based on an inverted device structure that utilizes a self-assembled fullerene monolayer (C-60-SAM) as the cathode modification layer, and an efficient and highly stable OSC composes of a polymer donor of poly[4,8-bis (5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:5,6-b'] dithiophene-alt-3-fluorothie-no [3,4-b]thiophene-2-carboxylate] (PTB7-Th) and a non-fullerene acceptor of (2,2'4(2Z,2'Z)-(((4,4,9,9-Tetrakis(4-hexylphenyl)-4,9-dihydro-sindaceno[1,2-b:5,6-b']dithiophene-2,7-diyl)bis(44(2ethylhexyl)oxy)thiophene-5,2-diyl))-bis(methanylylidene))bis(5,6-difluoro-3-oxo-2,3-dihydro-1H-indene -2,1-diylidene))dimalononitrile) (IEICO-4F) is presented, showing a PCE of 10%. It further achieves an extrapolated T-80 lifetime (the time required to reach 80% of initial performance) of 34,000 h, operating under one sun illumination equivalent. Based on an estimated solar irradiance of 1500 kWh/(m(2) year) for China, a potential lifetime of 22 years is inferred for the OSC. Further investigation reveals that the reported C-60-SAM modification stabilizes the OSC active layer morphology by lowering the surface energy of the underlying ZnO electron transport layer and suppressing trap-assisted recombination, thereby improving photostability. The results of this work establish important guidelines for the development of non-fullerene based OSCs with enhanced stability and pave the way for the commercialization of OSC technology.

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