Fabrication and thermal properties of CaCl2?6H2O-CO(NH2)2/SiO 2 as room-temperature shape-stable composite PCM for building thermal insulation

作者：Fang, Yutang^*; Wang, Kai; Ding, Yifan; Liang, Xianghui; Wang, Shuangfeng; Gao, Xuenong; Zhang, Zhengguo

来源：Solar Energy Materials and Solar Cells, 2021, 232: 111355.

DOI：10.1016/j.solmat.2021.111355

• Form-stable composite PCM
• CaCl2 center dot 6H(2)O
• Hydrophilic fumed silica
• Phase change temperature regulator
• Indoor building insulation

The combination of room-temperature phase change materials (PCMs) and building materials can reduce the energy consumption of heating equipment and improve indoor thermal comfort. In this paper, the novel CaCl2 center dot 6H(2)O -CO(NH2)(2)/SiO2 room-temperature shape-stable composite PCM was fabricated by melt-blending method with CaCl2 center dot 6H(2)O as the basic PCM, CO(NH2)(2) as the phase change temperature regulator and hydrophilic fumed silica (SiO2) as the carrier. The temperature-regulating effect of CO(NH2)(2) on CaCl2 center dot 6H(2)O and the shape-stabilizing effect of SiO2 on CaCl2 center dot 6H(2)O -CO(NH2)(2) PCM were emphatically analyzed. The results revealed that the obtained composite PCM with 6% CO(NH2)(2) and 20% SiO2 possessed a favorable form-stability, relatively high enthalpy (114.3 J g(-1)) and appropriate phase change temperature (21.03 degrees C) which decreased by 7.81 degrees C compared with pure CaCl2 center dot 6H(2)O (28.84 degrees C). Furthermore, its small supercooling degree (0.259 degrees C), low thermal conductivity (0.3667 W.m(-1).K-1) as well as the excellent cyclic reliability and thermal stability indicated that the composite PCM has good thermodynamic properties, enabling its application for indoor building thermal insulation and even some other areas.